Control of the mode selectivity (ene reaction versus [2+2] cycloaddition) in the photooxygenation of ene carbamates: Directing effect of an alkenylic nitrogen functionality

被引：32

作者：

Adam, W

Bosio, SG

Turro, NJ

机构：

[1] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany

[2] Columbia Univ, Dept Chem, New York, NY 10027 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 47期

关键词：

D O I：

10.1021/ja028407m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The geometry of the double bond in oxazolidinone-substituted ene carbamates controls the mode selectivity (ene reaction versus [2+2] cycloaddition) of singlet oxygen through stereoelectronic effects, whereas the chiral auxiliary provides high diastereoselectivity through steric shielding. Copyright © 2002 American Chemical Society.

引用

页码：14004 / 14005

页数：2

共 16 条

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