The effect of Li and La on NiO/Al2O3 catalyst for CH4/O2 to syngas reaction

被引：16

作者：

Liu, SL ^{[1
]}

Xiong, GX ^{[1
]}

Yang, WS ^{[1
]}

Sheng, SS ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1999年 / 68卷 / 02期

关键词：

methane partial oxidation; nickel-based catalysts; stability; sintering and loss of nickel;

D O I：

10.1007/BF02475508

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The thermal stability and an 80 h life test over nickel-based catalysts for CH4/O-2 to syngas reaction were investigated by flow-reactor, XPS, XRD and AAS analysis. The results indicate that the introduction of Li and La not only stabilized the support gamma-Al2O3 phase, but also suppressed the sintering and loss of nickel, and in addition, enhanced the ability to suppress the carbon-deposition over NiO/Al2O3 during the high-temperature reaction.

引用

页码：243 / 247

页数：5

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