Ni(II) complexes containing chiral tridentate phosphines as new catalysts for the hydroamination of activated olefins

被引：207

作者：

Fadini, L ^{[1
]}

Togni, A ^{[1
]}

机构：

[1] ETH Honggerberg, Swiss Fed Inst Technol, Dept Chem, CH-8093 Zurich, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 01期

关键词：

D O I：

10.1039/b210680a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ni(II) complexes containing chiral tridentate ferrocenyl phosphines (Ni(PPP)) have been found to efficiently catalyse the hydroamination of activated olefins with both anilines and aliphatic amines at r.t. (TON up to 71, TOF up to ca. 3 h(-1), and enantioselectivities up to 69% ee).

引用

页码：30 / 31

页数：2

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