Strontium isotope evolution of Late Permian and Triassic seawater

The Sr-87/Sr-86 values based on brachiopods and conodonts define a nearly continuous record for the Late Permian and Triassic intervals. Minor gaps in measurements exist only for the uppermost Brahmanian, lower part of the Upper Olenekian, and Middle Norian, and only sparse data are available for the Late Permian. These 219 measurements include 67 brachiopods and 114 conodont samples from the Tethyan realm as well as 37 brachiopods and one conodont sample from the mid-European Middle Triassic Muschelkalk Sea. The Late Permian/Lower Triassic interval is characterized by a steep 1.3 x 10(-3) rise, from 0.7070 at the base of the Dzhulfian to 0.7082 in the late Olenekian, a rate of change comparable to that in the Cenozoic. In the mid-Triassic (Anisian and Ladinian), the isotope values fall to 0.7075, followed again by a rise to 0.7081 in the Middle/Late Norian. The Sr-87/Sr-86 values decline again in the Late Norian (Sevatian) and Rhaetian to 0.7076. The sharp rise in the Sr-87/(86) Sr values during the Late Permian/Early Triassic was coincident with widespread clastic sedimentation. Because of the paucity of tectonic uplifts, the enhanced erosion may have been due to intermittent humid phases, during mainly an and interval, coupled with the absence of a dense protective land plant cover following the mass extinction during the latest Permian. The apex of the Sr-87/Sr-86 curve at the Olenekian/Anisian boundary coincides with cessation of the large-scale clastic sedimentation and also marks the final recovery of land vegetation, as indicated by the renewed onset of coal formation in the Middle Triassic. The rising Sr-87/Sr-86 values from the Middle Carnian to the Late Norian coincide with the uplift and erosion of the Cimmeride-Indosinian orogens marking the closure of the Palaeotethys. The subsequent Rhaetian decline that continues into Jurassic (Pliensbachian/Toarcian boundary), on the other hand, coincides with the opening of the Vardar Ocean and its eastern continuation in the Izmir-Ankara Ophiolitic Belt. Samples from the Upper Muschelkalk are more radiogenic than the global trend. This may reflect separation of the basin from the open ocean. Due to strong meteoric influx from a large land mass in the north, the Germanic Basin became increasing brackish up section in the north and east, but because of the high evaporation rates, the salt content was not much reduced in the southern and central basin where a rich, but increasingly endemic, marine fauna survived. Copyright (C) 2003 Elsevier Science Ltd.