Metal foams as flow field and gas diffusion layer in direct methanol fuel cells

被引:98
作者
Arisetty, Srikanth [1 ]
Prasad, Ajay K. [1 ]
Advani, Suresh G. [1 ]
机构
[1] Univ Delaware, Fuel Cell Res Lab, Dept Mech Engn, Newark, DE 19716 USA
关键词
direct methanol fuel cells; metal foam; gas diffusion layer; bipolar plates; multifunctional; composites;
D O I
10.1016/j.jpowsour.2006.12.008
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 [物理化学]; 081704 [应用化学];
摘要
Metal foams are routinely used in structures to enhance stiffness and reduce weight over a range of platforms. In direct methanol fuel cells, the controlled porosity and high electrical conductivity of metal foams provide additional benefits. Performance studies were conducted with direct methanol fuel cells incorporating metal foams as the flow field. The influence of the foam pore size and density on cell performance was investigated. The performance of similar density metal foams but with different pore sizes was non-monotonic due to the opposing trends of electrical contact and CO2 removal with pore size. In contrast, for metal foams with the same in-plane pore size, the performance improved with increasing density. Because the cell operates in a diffusion-dominated regime, its performance showed a strong dependence on methanol concentration and a moderate dependence on methanol flow rate. The feasibility of using metal foams as a gas diffusion layer (GDL) was also explored. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:49 / 57
页数:9
相关论文
共 17 条
[1]
Gas evolution and power performance in direct methanol fuel cells [J].
P. Argyropoulos ;
K. Scott ;
W.M. Taama .
Journal of Applied Electrochemistry, 1999, 29 (6) :663-671
[2]
Carbon dioxide evolution patterns in direct methanol fuel cells [J].
Argyropoulos, P ;
Scott, K ;
Taama, WM .
ELECTROCHIMICA ACTA, 1999, 44 (20) :3575-3584
[3]
Influence of flow field design on the performance of a direct methanol fuel cell [J].
Aricò, AS ;
Cretì, P ;
Baglio, V ;
Modica, E ;
Antonucci, V .
JOURNAL OF POWER SOURCES, 2000, 91 (02) :202-209
[4]
Bipolar plate materials for solid polymer fuel cells [J].
Davies, DP ;
Adcock, PL ;
Turpin, M ;
Rowen, SJ .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2000, 30 (01) :101-105
[5]
Experimental studies of a direct methanol fuel cell [J].
Ge, JB ;
Liu, HT .
JOURNAL OF POWER SOURCES, 2005, 142 (1-2) :56-69
[6]
Performance and methanol permeation of direct methanol fuel cells:: dependence on operating conditions and on electrode structure [J].
Gogel, V ;
Frey, T ;
Zhu, YS ;
Friedrich, KA ;
Jörissen, L ;
Garche, J .
JOURNAL OF POWER SOURCES, 2004, 127 (1-2) :172-180
[7]
Materials and design development for bipolar/end plates in fuel cells [J].
Kumar, A ;
Reddy, RG .
JOURNAL OF POWER SOURCES, 2004, 129 (01) :62-67
[8]
Modeling of polymer electrolyte membrane fuel cell with metal foam in the flow-field of the bipolar/end plates [J].
Kumar, A ;
Reddy, RG .
JOURNAL OF POWER SOURCES, 2003, 114 (01) :54-62
[9]
Effect of oscillatory frequency on heat transfer in metal foam heat sinks of various pore densities [J].
Leong, KC ;
Jin, LW .
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2006, 49 (3-4) :671-681
[10]
Use of stainless steel for cost competitive bipolar plates in the SPFC [J].
Makkus, RC ;
Janssen, AHH ;
de Bruijn, FA ;
Mallant, RKAM .
JOURNAL OF POWER SOURCES, 2000, 86 (1-2) :274-282