Hierarchical structures of a synthetic rodlike polyelectrolyte in water

被引:58
作者
Bockstaller, M
Köhler, W
Wegner, G
Vlassopoulos, D
Fytas, G
机构
[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
[2] Univ Bayreuth, Inst Phys, D-95440 Bayreuth, Germany
[3] FORTH, Inst Elect Struct & Laser, Iraklion 71110, Crete, Greece
关键词
D O I
10.1021/ma000190y
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A simple synthetic model system that mimics some of the principal phenomena governing interactions between highly charged systems is introduced. The system consists of a rigid poly(p-phenylene) backbone with sulfonate and dodecyl side groups (PPPS). In water, the system forms cylindrical micelles of defined radial aggregation number Nrad approx. 1110 with a negatively charged surface on account of the sulfonate groups.
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页码:3951 / 3953
页数:3
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