Coordination-number dependence of reactivity in an imidoiron(III) complex

被引：138

作者：

Eckert, Nathan A.

Vaddadi, Sridhar

Stoian, Sebastian

Lachicotte, Rene J.

Cundari, Thomas R. ^{[1
]}

Holland, Patrick L.

机构：

[1] Univ N Texas, Dept Chem, Denton, TX 76203 USA

[2] Univ Rochester, Dept Chem, Rochester, NY 14627 USA

[3] Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 41期

关键词：

coordination number; hydrogen-atom abstraction; imido ligands; iron;

D O I：

10.1002/anie.200601927

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Reaction of the {LMeFe} fragment with adamantyl azide (AdN3) in the presence of 4-tert-butylpyridine (tBuPy) gives an S = 3/2 species that has been examined by 1H NMR, IR, EPR, and Mössbauer spectroscopies. DFT calculations point toward an identification as [LMeFeNAd]. This species abstracts hydrogen atoms from the ligand or external reagents only through its pyridine adduct (see scheme; Ar = 2,6-iPr2C6H3). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6868 / 6871

页数：4

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