Synthesis, characterisation and ligand properties of a new amphiphilic triphenylphosphine analogue

被引：24

作者：

Karlsson, M ^{[1
]}

Johansson, M ^{[1
]}

Andersson, C ^{[1
]}

机构：

[1] Lund Univ, Inorgan Chem Chem Ctr 1, S-22100 Lund, Sweden

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 23期

关键词：

D O I：

10.1039/a908077e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

{4-[Bis(2-diethylaminoethyl)aminomethyl]diphenyl}phosphine, N3P, an analogue of triphenylphosphine (TPP) with amphiphilic character, was synthesized and characterised. Its metal complexes [Rh(CO)(N3P)(acac)] and cis-[PtCl(2)(N3P)(2)] have been prepared and the crystal structure of the former determined. The feasibility of catalysts formed in situ from [Rh(CO)(2)(acac)] and N3P in the hydroformylation of 1-hexene under homogeneous and biphasic conditions is also demonstrated.

引用

页码：4187 / 4192

页数：6

共 40 条

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