Synthesis and structural characterization of (pseudo)-halo adducts of (η4-1,5-cyclooctadiene)(1,3-dimethylimidazolin-2-ylidine)rhodium

被引:32
作者
Baker, MV [1 ]
Brayshaw, SK [1 ]
Skelton, BW [1 ]
White, AH [1 ]
机构
[1] Univ Western Australia, Sch Biomed & Chem Sci, Crawley, WA 6009, Australia
基金
澳大利亚研究理事会;
关键词
nickel compounds; crystal structures; spectroscopic studies; magnetic studies;
D O I
10.1016/j.ica.2003.11.031
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A series of compounds [(COD)(Me(2)m)RhX] (Me(2)Im = 1,3-dimethylimidazolin-2-ylidine, X = Cl, Br, I, N-3, NCO, SCN, SeCN) have been prepared and examined using X-ray diffraction and NMR spectroscopy. The synthesis and structure of [(COD) (Me(2)Bm)RhCl] (Me(2)Bm = 1,3-dimethylbenzimidazolin-2-ylidine) are also reported. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:2841 / 2849
页数:9
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