Optical sensors based on nanostructured cage materials for the detection of toxic metal ions

被引:209
作者
Balaji, Tatineni [1 ]
El-Safty, Sherif A. [1 ]
Matsunaga, Hideyuki [1 ]
Hanaoka, Takaaki [1 ]
Mizukami, Fujio [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, AIST, Res Ctr Compact Chem Proc, Miyagino Ku, Sendai, Miyagi 9838551, Japan
关键词
cage monoliths; colorimetry; environmental chemistry; sensors; toxic metal ions;
D O I
10.1002/anie.200602453
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Seeing red: Highly sensitive and selective chemical sensing systems were developed for the naked-eye detection of toxic ions by the direct and indirect postgrafting of hydrophilic and hydrophobic chromophores into spherically nanosized cavities of cubic Fm3m monoliths (HOM-C10). This leads to reliable control over the visual detection of toxic metals such as PbII, CdII, SbIII, and HgII ions at a low concentrations (≈10-9 M). DZ = diphenylthiocarbazone. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:7202 / 7208
页数:7
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