An oxime-carbapalladacycle complex covalently anchored to silica as an active and reusable heterogeneous catalyst for Suzuki cross-coupling in water

被引：172

作者：

Baleizao, C

Corma, A

García, H

Leyva, A

机构：

[1] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain

[2] INETI DTIQ, P-1649038 Lisbon, Portugal

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 05期

关键词：

D O I：

10.1039/b211742h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A preformed oxime-carbapalladacycle complex covalently anchored onto mercaptopropyl modified silica is highly active ( > 99%) for the Suzuki reaction of p-chloroacetophenone and phenylboronic acid in water; no leaching occurs and the same catalyst sample was reused eight times without decreased activity.

引用

页码：606 / 607

页数：2

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