AlCl3•6H2O/KI/H2O/CH3CN:: A new alternate system for dehydration of oximes and amides in hydrated media

被引：89

作者：

Boruah, M ^{[1
]}

Konwar, D ^{[1
]}

机构：

[1] Reg Res Lab, Div Organ Chem, Jorhat 785006, Assam, India

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 67卷 / 20期

关键词：

D O I：

10.1021/jo020005+

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dehydration of oximes and amides to nitriles was carried out using the AlC3.6H(2)O/KI/H2O/CH3CN system. It produced isoquinoline derivatives 8a-c (Bischler Naperialski reaction) when reacted with amides 7a-c in hydrated media. Also, the keto oximes produced anilides (Beckmann rearrangement) with the system under the same reaction conditions.

引用

页码：7138 / 7139

页数：2

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