Fundamental principles of selective heterogeneous oxidation atalysis

被引：387

作者：

Grasselli, RK ^{[1
]}

机构：

[1] Univ Delaware, Dept Chem Engn, Newark, DE 19716 USA

[2] Univ Delaware, Dept Mat Sci, Newark, DE 19716 USA

[3] Univ Munich, Inst Chem Phys, D-81377 Munich, Germany

来源：

TOPICS IN CATALYSIS | 2002年 / 21卷 / 1-3期

关键词：

lattice oxygen; metal oxygen bond; host structure; redox; multifunctionality; site isolation; phase cooperation; oxidation; ammoxidation; acrolein; acrylonitrile; molybdates; antimonates;

D O I：

10.1023/A:1020556131984

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Seven principles (seven pillars) underpinning selective heterogeneous oxidation catalysis, comprising lattice oxygen, metal oxygen bond strength, host structure, redox, multifunctionality of active sites, site isolation, and phase cooperation are described. Their intended utilization towards a deeper understanding of metal oxide catalyst behavior and application towards catalyst design are indicated.

引用

页码：79 / 88

页数：10

共 57 条

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ANDERSON A, 1992, P 10 INT C CAT, pA691

[2] The importance of site isolation and phase cooperation in propane ammoxidation on rutile-type vanadia catalysts [J].