Optical-limiting properties of a push-pull diphenyl-butadiene

被引:25
作者
Oberlé, J [1 ]
Bramerie, L [1 ]
Jonusauskas, G [1 ]
Rullière, C [1 ]
机构
[1] Univ Bordeaux 1, Ctr Phys Mol Opt & Hertzienne, CNRS, UMR 5798, F-33405 Talence, France
关键词
optical limiting; two-photon absorption; diphenyl-butadiene; picosecond spectroscopy; nonlinear transmission;
D O I
10.1016/S0030-4018(99)00364-8
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The optical-limiting behavior of 1-(p-N,N-dimethylamino)-4-( p-cyanophenyl)-1,3-butadiene (DCB) solution in dichloromethane was experimentally and theoretically studied at 532 nm with nanosecond and picosecond pulses. Energy-dependent transmissivity measurements were fitted using a three-level molecular model including two-photon absorption. The best fits were obtained with very high two-photon absorption cross-sections, indicating that two-photon absorption is the predominant mechanism of the strong optical limiting behavior observed in a DCB solution. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:325 / 332
页数:8
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