Molecular braids: quintuple helical hydrogen bonded molecular network

被引:66
作者
Jaunky, W
Hosseini, MW [1 ]
Planeix, JM
De Cian, A
Kyritsakas, N
Fischer, J
机构
[1] Univ Strasbourg, Chim Coordinat Organ Lab, CNRS, UMR 7512, F-67000 Strasbourg, France
[2] Univ Strasbourg, Lab Cristallochim & Chim Struct, CNRS, UMR 7512, F-67000 Strasbourg, France
关键词
D O I
10.1039/a906728k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis of 1, characterized by a calix[4]arene backbone in 1,3-alternate conformation bearing four pyridines acting as hydrogen bond acceptors, was achieved and its solid state structure studied by X-ray diffraction on a single crystal; in the presence of 4,4'-biphenol 6 acting as a dihydrogen bond donor, compound 1 formed infinite single strand helical 1-D molecular networks which upon lateral association were packed in the crystalline phase as quintuple helices.
引用
收藏
页码:2313 / 2314
页数:2
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