PM10 source apportionment applying PMF and chemical tracer analysis to ship-borne measurements in the Western Mediterranean

被引：54

作者：

Bove, M. C. ^{[1
]}

Brotto, P. ^{[1
]}

Calzolai, G. ^{[3
]}

Cassola, F. ^{[1
]}

Cavalli, F. ^{[2
]}

Fermo, P. ^{[4
]}

Hjorth, J. ^{[2
]}

Massabo, D. ^{[1
]}

Nava, S. ^{[3
]}

Piazzalunga, A. ^{[5
]}

Schembari, C. ^{[2
]}

Prati, P. ^{[1
]}

机构：

[1] Univ Genoa, Dept Phys, Ist Nazl Fis Nucl, I-16146 Genoa, Italy

[2] Commiss European Communities, JRC, IES, Air & Climate Unit, I-21027 Ispra, VA, Italy

[3] Univ Florence, Dept Phys & Astron, Ist Nazl Fis Nucl, I-50019 Sesto Fiorentino, FI, Italy

[4] Univ Milan, Dept Chem, I-20133 Milan, Italy

[5] Univ Milano Bicocca, Dept Earth & Environm Sci, I-20126 Milan, Italy

来源：

ATMOSPHERIC ENVIRONMENT | 2016年 / 125卷

关键词：

PM10; Ship emissions; Mediterranean basin; Source apportionment; POSITIVE MATRIX FACTORIZATION; AIRBORNE PARTICULATE MATTER; FACTOR-ANALYTIC MODELS; AEROSOL-PARTICLES; AIR-POLLUTION; PM2.5; SEA; SULFATE; EMISSIONS; METHANESULFONATE;

D O I：

10.1016/j.atmosenv.2015.11.009

中图分类号：

X [环境科学、安全科学];

学科分类号：

083001 [环境科学];

摘要：

A PM10 sampling campaign was carried out on board the cruise ship Costa Concordia during three weeks in summer 2011. The ship route was Civitavecchia-Savona-Barcelona-Palma de Mallorca-Malta (Valletta)-Palermo-Civitavecchia. The PM10 composition was measured and utilized to identify and characterize the main PM10 sources along the ship route through receptor modelling, making use of the Positive Matrix Factorization (PMF) algorithm. A particular attention was given to the emissions related to heavy fuel oil combustion by ships, which is known to be also an important source of secondary sulphate aerosol. Five aerosol sources were resolved by the PMF analysis. The primary contribution of ship emissions to PM10 turned out to be (12 +/- 4)%, while secondary ammonium sulphate contributed by (35 +/- 5)%. Approximately, 60% of the total sulphate was identified as secondary aerosol while about 20% was attributed to heavy oil combustion in ship engines. The measured concentrations of methanesulphonic acid (MSA) indicated a relevant contribution to the observed sulphate loading by biogenic sulphate, formed by the atmospheric oxidation of dimethyl sulphide (DMS) emitted by marine phytoplankton. (c) 2015 Elsevier Ltd. All rights reserved.

引用

页码：140 / 151

页数：12

共 51 条

[1]

Emission measurements from a crude oil tanker at sea [J].

Agrawal, Harshit ;

Welch, William A. ;

Miller, J. Wayne ;

Cocker, David R. .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2008, 42 (19) :7098-7103

[2]

Primary Particulate Matter from Ocean-Going Engines in the Southern California Air Basin [J].

Agrawal, Harshit ;

Eden, Rudy ;

Zhang, Xinqiu ;

Fine, Philip M. ;

Katzenstein, Aaron ;

Miller, J. Wayne ;

Ospital, Jean ;

Teffera, Solomon ;

Cocker, David R., III .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2009, 43 (14) :5398-5402

[3]

[Anonymous], 2020, Gothenburg Protocol to reduce transboundary air pollution, DOI DOI 10.5860/CHOICE.44-4512

[4]

[Anonymous], USERS GUIDE POSITI 1

[5]

Elemental characterization of PM10, PM2.5 and PM1 in the town of Genoa (Italy) [J].

Ariola, V ;

D'Alessandro, A ;

Lucarelli, F ;

Marcazzan, G ;

Mazzei, F ;

Nava, S ;

Garcia-Orellana, I ;

Prati, P ;

Valli, G ;

Vecchi, R ;

Zucchiatti, A .

CHEMOSPHERE, 2006, 62 (02) :226-232

[6]

VARIATIONS IN THE METHANESULFONATE TO SULFATE MOLAR RATIO IN SUBMICROMETER MARINE AEROSOL-PARTICLES OVER THE SOUTH-PACIFIC OCEAN [J].

BATES, TS ;

CALHOUN, JA ;

QUINN, PK .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1992, 97 (D9) :9859-9865

[7]

Evidence for heavy fuel oil combustion aerosols from chemical analyses at the island of Lampedusa: a possible large role of ships emissions in the Mediterranean [J].

Becagli, S. ;

Sferlazzo, D. M. ;

Pace, G. ;

di Sarra, A. ;

Bommarito, C. ;

Calzolai, G. ;

Ghedini, C. ;

Lucarelli, F. ;

Meloni, D. ;

Monteleone, F. ;

Severi, M. ;

Traversi, R. ;

Udisti, R. .

ATMOSPHERIC CHEMISTRY AND PHYSICS, 2012, 12 (07) :3479-3492

[8]

Sources for PM air pollution in the Po Plain, Italy: I. Critical comparison of methods for estimating biomass burning contributions to benzo(a)pyrene [J].

Belis, C. A. ;

Cancelinha, J. ;

Duane, M. ;

Forcina, V. ;

Pedroni, V. ;

Passarella, R. ;

Tanet, G. ;

Douglas, K. ;

Piazzalunga, A. ;

Bolzacchini, E. ;

Sangiorgi, G. ;

Perrone, M. -G. ;

Ferrero, L. ;

Fermo, P. ;

Larsen, B. R. .

ATMOSPHERIC ENVIRONMENT, 2011, 45 (39) :7266-7275

[9]

Seasonal variability of the elemental composition of atmospheric aerosol particles over the northwestern Mediterranean [J].

Bergametti, Gilles ;

Dutot, Alain-Louis ;

Buat-Menard, Patrick ;

Losno, Remi ;

Remoudaki, Emmanouela .

TELLUS SERIES B-CHEMICAL AND PHYSICAL METEOROLOGY, 1989, 41 (03) :353-361

[10]

An integrated PM2.5 source apportionment study: Positive Matrix Factorisation vs. the chemical transport model CAMx [J].

Bove, M. C. ;

Brotto, P. ;

Cassola, F. ;

Cuccia, E. ;

Massabo, D. ;

Mazzino, A. ;

Piazzalunga, A. ;

Prati, P. .

ATMOSPHERIC ENVIRONMENT, 2014, 94 :274-286

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