Stationary flow conditions in pulsed supersonic beams

被引:10
作者
Christen, Wolfgang [1 ]
机构
[1] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany
关键词
FREE-JET EXPANSION; INFRARED-ABSORPTION SPECTROSCOPY; STEADY GAS INJECTION; OPTICAL-PATH LENGTH; MOLECULAR-BEAM; LAVAL NOZZLE; SLIT NOZZLE; LASER SPECTROSCOPY; VALVE APPROPRIATE; CLUSTER-SURFACE;
D O I
10.1063/1.4824155
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We describe a generally applicable method for the experimental determination of stationary flow conditions in pulsed supersonic beams, utilizing time-resolved electron induced fluorescence measurements of high pressure jet expansions of helium. The detection of ultraviolet photons from electronically excited helium emitted very close to the nozzle exit images the valve opening behavior-with the decided advantage that a photon signal is not affected by beam-skimmer and beam-residual gas interactions; it thus allows to conclusively determine those operation parameters of a pulsed valve that yield complete opening. The studies reveal that a "flat-top" signal, indicating constant density and commonly considered as experimental criterion for continuous flow, is insufficient. Moreover, translational temperature and mean terminal flow velocity turn out to be significantly more sensitive in testing for the equivalent behavior of a continuous nozzle source. Based on the widely distributed Even-Lavie valve we demonstrate that, in principle, it is possible to achieve quasi-continuous flow conditions even with fast-acting valves; however, the two prerequisites are a minimum pulse duration that is much longer than standard practice and previous estimates, and a suitable tagging of the appropriate beam segment. (C) 2013 AIP Publishing LLC.
引用
收藏
页数:11
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