Highly Efficient Incorporation of Functional Groups into Aromatic Main-Chain Polymer Using Iridium-Catalyzed C-H Activation and Suzuki-Miyaura Reaction

被引：72

作者：

Jo, Tae Soo ^{[1
]}

Kim, Se Hye ^{[1
]}

Shin, Jihoon ^{[1
]}

Bae, Chulsung ^{[1
]}

机构：

[1] Univ Nevada, Dept Chem, Las Vegas, NV 89154 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 05期

基金：

美国国家科学基金会;

关键词：

CROSS-COUPLING REACTIONS; POLYSULFONES; BORYLATION; MEMBRANES; ARENES; SYSTEMS;

D O I：

10.1021/ja808374e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a mild, iridium-catalyzed borylation of aromatic polysulfone with bis(pinacolato)diboron [B-2(pin)(2)] to form the corresponding borylated polysulfones up to high concentrations with nearly constant efficiency. The Suzuki-Miyaura cross-coupling reactions of the borylated polysulfones with functionalized aryl bromides allows installation of various functional groups such as ketone, amine, hydroxyl, and aldehyde to the polysulfone main chain in excellent conversion.

引用

页码：1656 / +

页数：3

共 22 条

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