Vibrational spectroscopic studies of the isotope effects in polyaniline

被引:152
作者
Quillard, S
Louarn, G
Buisson, JP
Boyer, M
Lapkowski, M
Pron, A
Lefrant, S
机构
[1] SILESIAN TECH UNIV,DEPT CHEM,PL-44100 GLIWICE,POLAND
[2] ACAD MIN & MET,PL-30059 KRAKOW,POLAND
[3] TECH UNIV WARSAW,PL-00664 WARSAW,POLAND
关键词
polyaniline; isotope effects; deuteration; vibrational spectroscopy;
D O I
10.1016/S0379-6779(96)04155-0
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Comparative Raman spectroscopy studies of nondeuterated polyaniline and polyaniline deuterated on the ring and on the nitrogen enabled us to confirm the assignments of principal Raman modes. Spectroelectrochemical studies carried out for these two isotopically different polymers indicate the creation of two types of structures upon electrochemical doping, namely polaron lattice and bipolaronic structure.
引用
收藏
页码:805 / 806
页数:2
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