Correlation states of propene

被引：9

作者：

Bawagan, ADO ^{[1
]}

Desjardins, SJ ^{[1
]}

Dailey, R ^{[1
]}

Davidson, ER ^{[1
]}

机构：

[1] INDIANA UNIV,DEPT CHEM,BLOOMINGTON,IN 47405

来源：

JOURNAL OF CHEMICAL PHYSICS | 1997年 / 107卷 / 11期

关键词：

D O I：

10.1063/1.474770

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

High resolution synchrotron photoelectron spectra (PES) of propene (C3H6) have been obtained at several photon energies (40-70 eV). The full valence shell binding energy spectrum reveals a well resolved correlation (satellite) peak at 20.3 eV and the photon energy dependence study of its photoionization cross section indicates that this new correlation peak is a ''dynamic'' correlation peak. MRSDCI calculations of the theoretical spectrum show semi-quantitative agreement between experiment and theory in terms of binding energies and intensities. A comparison of the full valence shell photoelectron spectra of ethylene, propene, 1-butene and 1,2-propadiene (allene) is also presented to illustrate trends in the correlation peaks of model alkenes. (C) 1997 American Institute of Physics.

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页码：4295 / 4306

页数：12

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