Crystallization and precipitation

被引:116
作者
Mersmann, A [1 ]
机构
[1] Tech Univ Munich, Dept Chem Engn B, D-85748 Garching, Germany
关键词
crystal growth; nucleation; agglomeration; median crystal size;
D O I
10.1016/S0255-2701(99)00025-2
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
This paper deals with the design and operation of cooling and evaporation crystallizers and precipitators for reaction crystallization. It will be shown that the median crystal size, L-50, of a crystalline product and the crystal size distribution (CSD) mainly depend on the crystallization kinetics, e.g. the rates of nucleation and crystal growth, and that these kinetics are controlled by supersaturation. Therefore, the main objective in crystallization and precipitation is to choose and to maintain the optimal supersaturation with respect to product quality at all times and all locations in the crystallizer or precipitator. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:345 / 353
页数:9
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