Calixarene-coated piezoelectric quartz crystal sensor for the detection of organic amine in liquids

被引：31

作者：

Chen, LX ^{[1
]}

He, XW ^{[1
]}

Hu, XB ^{[1
]}

Xu, H ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

来源：

ANALYST | 1999年 / 124卷 / 12期

关键词：

D O I：

10.1039/a906300e

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Five calixarene compounds were applied as piezoelectric quartz crystal (PQC) sensory coatings for the selective detection of organic amines in liquids. The complexation based on the host-guest interaction between the calixarene coating and the analyte makes the coated PQC sensors sensitive to organic amines and results in quasi-irreversible frequency changes. The relative selectivity of the analytes is explained by the cavity inclusion of analyte molecule, complete or partial, or by steric hindrance interaction. A PQC sensor coated with a calixarene with an acetate ester group exhibits a nearly linear response for analytes in the concentration range 0-200 ppm.

引用

页码：1787 / 1790

页数：4

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