New Viologen Analogs: 1,4-Bis[2-(pyridin-4-yl)ethenyl]benzene Quaternary Salts

被引：14

作者：

Gutov, A. V. ^{[1
]}

Rusanov, E. B. ^{[1
]}

Chepeleva, L. V. ^{[1
]}

Garasevich, S. G. ^{[2
]}

Ryabitskii, A. B. ^{[1
]}

Chernega, A. N. ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, Inst Organ Chem, UA-02660 Kiev, Ukraine

[2] Taras Shevchenko Kiev Natl Univ, Kiev, Ukraine

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2009年 / 79卷 / 07期

关键词：

General Chemistry; Electronic Absorption Spectrum; Dimethyl Sulfate; Tetraphenylborate; Ethenyl;

D O I：

10.1134/S1070363209070196

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alkylation of 1,4-bis[2-(pyridin-4-yl)ethenyl]benzene with alkyl p-toluenesulfonates and dimethyl sulfate gave new viologen analogs, 1-alkyl-4-(2-{4-[2-(1-alkylpyridinium-4-yl)ethenyl]phenyl}ethenyl)pyridinium bis(p-toluenesulfonates) and sulfate. Their derivatives with tetrafluoroborate and tetraphenylborate ions were also obtained. Spectral properties of the synthesized compounds were examined, and their structure was determined by X-ray analysis.

引用

页码：1513 / 1518

页数：6

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