Lanthanide-containing molecular and supramolecular polymetallic functional assemblies

被引:983
作者
Bünzli, JCG
Piguet, C
机构
[1] Swiss Fed Inst Technol, Inst Mol & Biol Chem, CH-1015 Lausanne, Switzerland
[2] Univ Geneva, Dept Inorgan Analyt & Appl Chem, CH-1211 Geneva 4, Switzerland
关键词
D O I
10.1021/cr010299j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The rational design of discrete polymetallic lanthanide-containing assemblies exhibiting predetermined and well-defined chemical and/or physical properties was reported. Thus, much attention was focused on systems for which relevant structure-function correlations were discussed together with thermodynamic properties responsible for the formation of specific assemblies in solution. This paper covers two short reviews highlighting specific synthetic and magnetic concepts in d-f and f-f assemblies.
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页码:1897 / 1928
页数:32
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