Efficient cyclopropanation of C-60 starting from malonates

被引：296

作者：

Camps, X ^{[1
]}

Hirsch, A ^{[1
]}

机构：

[1] INST ORGAN CHEM,D-91054 ERLANGEN,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1997年 / 11期

关键词：

D O I：

10.1039/a702055d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The direct treatment of C-60 with malonates in the presence of CBr4 and diazabicyclo[5.4.0]undec-7-ene (DBU) leads to an efficient conversion to methanofullerenes, which is demonstrated with the syntheses of monoadducts and highly symmetric hexaadducts in good yields.

引用

页码：1595 / 1596

页数：2

共 19 条

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