Calculation of the conditions to get less than 2 g tar/mn3 in a fluidized bed biomass gasifier

被引:36
作者
Corella, Jose [1 ]
Toledo, Jose M. [1 ]
Molina, Gregorio [1 ]
机构
[1] Univ Complutense Madrid, Fac Chem, Dept Chem Engn, E-28040 Madrid, Spain
关键词
gasification; tar; circulating fluidized bed (CFB); biomass; gas cleaning; renewable energies;
D O I
10.1016/j.fuproc.2006.05.002
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The experimental conditions under which a fluidized bed biomass gasifier can generate a gas with a tar content below 2 g/m(n)(3) are analyzed by using and developing the model recently published for those gasifiers by Corella and Sanz [Fuel Process. Techn. 2005, 86, 1021-1053]. The analyzed experimental conditions were: the equivalence ratio, the partitioning of the air, between the primary and secondary flows, the location (height) of the inlet of the secondary air flow, the biomass moisture and the biomass flow rate. Results from the modelling work are presented for a given CFB biomass gasifier of commercial size. Some of these results are also being checked in a CFB biomass gasifier at small pilot plant scale. To obtain a gasification gas with a very low tar content the two most important experimental conditions are a high value for the equivalence ratio and a good in-gasifier material which determines the values of the kinetic constants of the reactions involved in the network at the gasifier. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:841 / 846
页数:6
相关论文
共 22 条
[1]   A comparison of Rh/CeO2/SiO2 catalysts with steam reforming catalysts, dolomite and inert materials as bed materials in low throughput fluidized bed gasification systems [J].
Asadullah, M ;
Miyazawa, T ;
Ito, S ;
Kunimori, K ;
Koyama, S ;
Tomishige, K .
BIOMASS & BIOENERGY, 2004, 26 (03) :269-279
[2]   Plastic waste elimination by co-gasification with coal and biomass in fluidized bed with air in pilot plant [J].
Aznar, MP ;
Caballero, MA ;
Sancho, JA ;
Francés, E .
FUEL PROCESSING TECHNOLOGY, 2006, 87 (05) :409-420
[3]   Commercial steam reforming catalysts to improve biomass gasification with steam-oxygen mixtures. 2. Catalytic tar removal [J].
Aznar, MP ;
Caballero, MA ;
Gil, J ;
Martin, JA ;
Corella, J .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1998, 37 (07) :2668-2680
[4]   On the relevance of axial and transversal fuel segregation during the FB combustion of a biomass [J].
Chirone, R ;
Miccio, F ;
Scala, F .
ENERGY & FUELS, 2004, 18 (04) :1108-1117
[5]   Modeling circulating fluidized bed biomass gasifiers. A pseudo-rigorous model for stationary state [J].
Corella, J ;
Sanz, A .
FUEL PROCESSING TECHNOLOGY, 2005, 86 (09) :1021-1053
[6]   Olivine or dolomite as in-bed additive in biomass gasification with air in a fluidized bed: Which is better? [J].
Corella, J ;
Toledo, JM ;
Padilla, R .
ENERGY & FUELS, 2004, 18 (03) :713-720
[7]   Two advanced models for the kinetics of the variation of the tar composition in its catalytic elimination in biomass gasification [J].
Corella, J ;
Caballero, MA ;
Aznar, MP ;
Brage, C .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2003, 42 (13) :3001-3011
[8]  
CORELLA J, 2001, 1 WORLD C BIOM EN IN, P1472
[9]  
CORELLA J, 2003, COMMUNICATION
[10]  
CORELLA J, 1990, BIOMASS ENERGY IND, P2804