Novel N,N'-bridged dithiadiazafulvalene trapped in situ as a cation radical salt with polyoxometalate: (DTDAF)(2)MO6O19

被引：27

作者：

Bellec, N

Lorcy, D

Robert, A

Carlier, R

Tallec, A

Rimbaud, C

Ouahab, L

Clerac, R

Delhaes, P

机构：

[1] UNIV RENNES 1,UMR 6510,F-35042 RENNES,FRANCE

[2] UNIV RENNES 1,UMR 6511,CHIM SOLIDE & INORGAN MOL LAB,F-35042 RENNES,FRANCE

[3] UNIV BORDEAUX 1,CTR RECH PAUL PASCAL,F-33600 PESSAC,FRANCE

[4] CNRS,CTR RECH PAUL PASCAL,F-33600 PESSAC,FRANCE

来源：

ADVANCED MATERIALS | 1997年 / 9卷 / 13期

关键词：

D O I：

10.1002/adma.19970091313

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Communication: A quasi-planar dithiadiazafulvalene (DTDAF) with high electrondonating properties is reported. The chemical synthesis of a phenyl-N,N'-bridge DTDAF (the Figure shows an ORTEP drawing of the DTDAF(+.) cation radical) is described together with the preparation of a charge-transfer salt by in situ trapping and investigations of the structural and magnetic properties of this salt. Evidence for mixed valence states is presented.

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页码：1052 / &

页数：6

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