Imposing curvature on a polyarene by intramolecular palladium-catalyzed arylation reactions:: A simple synthesis of dibenzo[a,g]corannulene

被引：112

作者：

Reisch, HA ^{[1
]}

Bratcher, MS ^{[1
]}

Scott, LT ^{[1
]}

机构：

[1] Boston Coll, Dept Chem, Merkert Chem Ctr, Chestnut Hill, MA 02467 USA

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 10期

关键词：

D O I：

10.1021/ol005755p

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Palladium catalysis has been found to offer an effective solution phase alternative to gas phase flash vacuum pyrolysis as a method for converting the planar ring system of 7,10-di(2-bromophenyl)fluoranthene (4) to that of the C28H14 bowl-shaped fullerene fragment dibenzo[a,g]corannulene (5).

引用

页码：1427 / 1430

页数：4

共 38 条

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