Unusual alkali metal α- or β-phenyl(trimethylsilyl)amides

被引：39

作者：

Antolini, F ^{[1
]}

Hitchcock, PB ^{[1
]}

Lappert, MF ^{[1
]}

Merle, P ^{[1
]}

机构：

[1] Univ Sussex, Chem Lab, Brighton BN1 9QJ, E Sussex, England

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 14期

关键词：

D O I：

10.1039/b003169k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis (1-3 and 5) and structures (1-5) of the crystalline, hydrocarbon-soluble metal amides [M{mu-N(SiMe3)(SiMe2Ph)}(NCBut)(n)](2) [n = 0 and M = Li 1 (cis), M = Na 2 (trans) having intermolecular Na ... C contacts, or n = 1 and M = Na (cis) 3], [Li{mu-N(SiMe3)Ph}-cis](2)[mu-{N(SiMe3)Ph}Li-cis](2) 4 and trans-[Na{mu-N(SiMe3)Ph}(tmen)] 5 are reported.

引用

页码：1301 / 1302

页数：2

共 16 条

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