A novel BEDT-TTF-based purely organic magnetic conductor, α-(BEDT-TTF)2(TEMPO-N(CH3)COCH2SO3)•3H2O

被引:19
作者
Akutsu, Hiroki
Yamada, Jun-Ichi
Nakatsuji, Shin'ichi
Tumer, Scott S.
机构
[1] Univ Hyogo, Grad Sch Mat Sci, Hyogo 6781297, Japan
[2] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
基金
日本学术振兴会;
关键词
organic crystals;
D O I
10.1016/j.ssc.2006.07.034
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
A new BEDT-TTF-based salt with an organic free radical TEMPO has been prepared. The salt consists of alternate layers of conducting and magnetic sheets, between which are short S(BEDT-TTF)...O(TEMPO) contacts. The magnetic susceptibility is well modelled by the combination of a 2D Heisenberg and a Curie-Weiss model with J = -89 K and theta = +0.05 K. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:256 / 260
页数:5
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