Regular arrays of microdisk electrodes: Numerical simulation as an optimizing tool to maximize the current response and minimize the electrode area used

被引:16
作者
Chevallier, Francois G. [1 ]
Compton, Richard G. [1 ]
机构
[1] Univ Oxford, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England
关键词
microdisk arrays; simulation; optimization;
D O I
10.1002/elan.200603683
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Microdisk electrode arrays constitute an interesting tool for electroanalysis and electrocatalysis due to their increased sensitivity and excellent limits of detection. We first demonstrate that a 2-dimensional simulation based on the diffusion domain approximation can be used to simulate the response of such electrochemical systems and therefore improve their design and fabrication process. Second, we report data showing the peak current response for arrays at three typically employed voltage scan rate as a function of the number of disks per unit area and their radii.
引用
收藏
页码:2369 / 2374
页数:6
相关论文
共 12 条
[1]   CHARGE-TRANSFER AT PARTIALLY BLOCKED SURFACES - A MODEL FOR THE CASE OF MICROSCOPIC ACTIVE AND INACTIVE SITES [J].
AMATORE, C ;
SAVEANT, JM ;
TESSIER, D .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1983, 147 (1-2) :39-51
[2]  
Bard A. J., 2000, ELECTROCHEMICAL METH
[3]   Computational and experimental study of the cyclic voltammetry response of partially blocked electrodes. Part 1. Nonoverlapping, uniformly distributed blocking systems [J].
Brookes, BA ;
Davies, TJ ;
Fisher, AC ;
Evans, RG ;
Wilkins, SJ ;
Yunus, K ;
Wadhawan, JD ;
Compton, RG .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (07) :1616-1627
[4]   Voltammetry at spatially heterogeneous electrodes [J].
Davies, TJ ;
Banks, CE ;
Compton, RG .
JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2005, 9 (12) :797-808
[5]   The cyclic and linear sweep voltammetry of regular and random arrays of microdisc electrodes: Theory [J].
Davies, TJ ;
Compton, RG .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2005, 585 (01) :63-82
[6]   The cyclic and linear sweep voltammetry of regular arrays of microdisc electrodes:: Fitting of experimental data [J].
Davies, TJ ;
Ward-Jones, S ;
Banks, CE ;
del Campo, J ;
Mas, R ;
Muñoz, FX ;
Compton, RG .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2005, 585 (01) :51-62
[7]   Regular arrays of microdisc electrodes:: simulation quantifies the fraction of 'dead' electrodes [J].
Ordeig, O ;
Banks, CE ;
Davies, TJ ;
del Campo, J ;
Mas, R ;
Muñoz, FX ;
Compton, RG .
ANALYST, 2006, 131 (03) :440-445
[8]   All-diamond microelectrode array device [J].
Pagels, M ;
Hall, CE ;
Lawrence, NS ;
Meredith, A ;
Jones, TGJ ;
Godfried, HP ;
Pickles, CSJ ;
Wilman, J ;
Banks, CE ;
Compton, RG ;
Jiang, L .
ANALYTICAL CHEMISTRY, 2005, 77 (11) :3705-3708
[9]   ENSEMBLES OF MICROELECTRODES - A DIGITAL-SIMULATION [J].
RELLER, H ;
KIROWAEISNER, E ;
GILEADI, E .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1982, 138 (01) :65-77
[10]   ENSEMBLES OF MICROELECTRODES - DIGITAL-SIMULATION BY THE TWO-DIMENSIONAL EXPANDING GRID METHOD - CYCLIC VOLTAMMETRY, IR EFFECTS AND APPLICATIONS [J].
RELLER, H ;
KIROWAEISNER, E ;
GILEADI, E .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 161 (02) :247-268