On the mechanism of isospecific epoxide polymerization by salen cobalt(III) complexes: Evidence for solid-state catalysis

被引：43

作者：

Ajiro, Hiroharu ^{[1
]}

Peretti, Kathryn L. ^{[1
]}

Lobkovsky, Emil B. ^{[1
]}

Coates, Geoffrey W. ^{[1
]}

机构：

[1] Cornell Univ, Baker Lab, Dept Chem & Chem Biol, Ithaca, NY 14853 USA

来源：

DALTON TRANSACTIONS | 2009年 / 41期

基金：

美国国家科学基金会;

关键词：

PROPYLENE-OXIDE POLYMERIZATION; ALTERNATING COPOLYMERIZATION; CO2;

D O I：

10.1039/b914573g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mechanistic studies have revealed that the isospecific polymerization of epoxides by a discrete salen cobalt(III) catalyst occurs at the surface of the undissolved, crystalline complex.

引用

页码：8828 / 8830

页数：3

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