Polyhedral oligomeric silsesquioxane (POSS) polymers and copolymers: A review

被引：977

作者：

Li, GZ ^{[1
]}

Wang, LC ^{[1
]}

Ni, HL ^{[1
]}

Pittman, CU ^{[1
]}

机构：

[1] Mississippi State Univ, Dept Chem, Mississippi State, MS 39762 USA

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2001年 / 11卷 / 03期

关键词：

polyhedral oligomeric silsesquioxane (POSS) polymers; POSS macromers; thermoplastics; thermosets; thermal and mechanical properties;

D O I：

10.1023/A:1015287910502

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This review describes the synthesis and properties of homopolymers and copolymers of monomers containing inorganic-organic hybrid polyhedral oligomeric silsesquioxane (POSS) structures. Monomers, such as styryl-POSS, methacrylate-POSS, norbornyl-POSS, vinyl-POSS, epoxy-POSS, and siloxane-POSS, are included. Both monofunctional and multifunctional monomers are included. Thermoplastic and thermoset systems are considered. Thermal, rheological, and dynamic mechanical properties are described. The synthesis of POSS macromers (monomers) is briefly described. POSS chemicals have been used to prepare nanosized designed novel composites with a variety of potential applications. This review, covering 111 references, is descriptive and not designed to be totally comprehensive. However, the major existing reviews of certain subtopics are noted, allowing the reader to gain a general introduction while providing the information to permit more comprehensive coverage.

引用

页码：123 / 154

页数：32

共 116 条

[1]

ADACHI E, 1992, Patent No. 4202290

[2]

ADACHI E, 1990, Patent No. 2277255

[3]

ADACHI E, 1989, Patent No. 1185924

[4]

ADACHI H, 1990, Patent No. 215863

[5]

ADACHI H, 1985, Patent No. 60108841

[6]

ADACHI H, 1985, REP PROG POLYM PHYS, V28, P261

[7]

ADACHI H, 1990, Patent No. 2222537

[8]

ADACHI H, 1986, REP PROG POLYM PHYS, V29, P257

[9]

ADACHI H, 1992, Patent No. 456975

[10]

ADACHI H, 1990, Patent No. 5087553

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