Inclusion behavior between molecular nanotubes and linear polymer chains in aqueous solutions

被引：37

作者：

Ikeda, E ^{[1
]}

Okumura, Y ^{[1
]}

Shimomura, T ^{[1
]}

Ito, K ^{[1
]}

Hayakawa, R ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Engn, Dept Appl Phys, Bunkyo Ku, Tokyo 113, Japan

来源：

JOURNAL OF CHEMICAL PHYSICS | 2000年 / 112卷 / 09期

关键词：

D O I：

10.1063/1.480978

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The inclusion behavior between molecular nanotubes and linear polymer chains in aqueous solutions is experimentally investigated by measuring the optical absorption spectra of the solutions with iodine as a probe. It is found that the amount of polymer chains included into nanotubes increases with polymer length, which indicates a molecular recognition of the nanotube for the polymer length in the complex formation. Furthermore, the experimental results are compared with a theory based on the Flory-Huggins lattice model. They are in good agreement with each other and the inclusion energy between the molecular nanotube and the linear polymer chain is evaluated. (C) 2000 American Institute of Physics. [S0021-9606(00)70309-6].

引用

页码：4321 / 4325

页数：5

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