Quantitative theory of surface tension and surface potential of aqueous solutions of electrolytes

被引：79

作者：

Markin, VS ^{[1
]}

Volkov, AG

机构：

[1] UT SW Med Ctr, Dept Anesthesiol, Dallas, TX 75390 USA

[2] Oakwood Coll, Dept Chem, Huntsville, AL 35896 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2002年 / 106卷 / 45期

关键词：

D O I：

10.1021/jp026229d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The surface tension and surface potential of aqueous solutions of inorganic electrolytes are calculated. The new model includes image forces at liquid interfaces, ions of finite radii, the hydrophobic effect, and the Parsons-Zobel effect. For the first time, a good correlation between theory and experimental data both qualitatively and quantitatively is obtained for different inorganic salts over a wide range of concentrations.

引用

页码：11810 / 11817

页数：8

共 40 条

[1] Tolman's δ, surface curvature, compressibility effects, and the free energy of drops [J].