Energy dissipation in small clusters: Direct photoemission, dissociation, and thermionic emission

被引:55
作者
Gantefor, G [1 ]
Eberhardt, W [1 ]
Weidele, H [1 ]
Kreisle, D [1 ]
Recknagel, E [1 ]
机构
[1] UNIV KONSTANZ, FAK PHYS, D-78434 CONSTANCE, GERMANY
关键词
D O I
10.1103/PhysRevLett.77.4524
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The competition between electron emission and unimolecular dissociation following the absorption of a single photon is studied for small clusters of various elements. Electron emission results from either direct photoemission, observed as a series of peaks in the spectrum, or thermionic emission, giving rise to a continuous background. Depending on the energetics involved, thermionic emission is in competition with evaporation of atoms. These results are compared to the corresponding events observed for solids, where the dominant decay products an inelastically scattered photoelectrons.
引用
收藏
页码:4524 / 4527
页数:4
相关论文
共 28 条
[1]   PHOTODISSOCIATION OF MASS-SELECTED (CO2)N-CLUSTERS - EVAPORATION LEADING TO MAGIC NUMBERS IN FRAGMENT-ION DISTRIBUTIONS [J].
ALEXANDER, ML ;
JOHNSON, MA ;
LEVINGER, NE ;
LINEBERGER, WC .
PHYSICAL REVIEW LETTERS, 1986, 57 (08) :976-979
[2]   DELAYED IONIZATION FOLLOWING PHOTOEXCITATION OF SMALL CLUSTERS OF REFRACTORY ELEMENTS - NANOFILAMENTS [J].
AMREIN, A ;
SIMPSON, R ;
HACKETT, P .
JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (06) :4663-4664
[3]   UNIMOLECULAR DECOMPOSITION OF SPUTTERED ALN+, CUN+, AND SIN+ CLUSTERS [J].
BEGEMANN, W ;
MEIWESBROER, KH ;
LUTZ, HO .
PHYSICAL REVIEW LETTERS, 1986, 56 (21) :2248-2251
[4]   PHOTOFRAGMENTATION OF MASS-RESOLVED SI-2-12(+) CLUSTERS [J].
BLOOMFIELD, LA ;
FREEMAN, RR ;
BROWN, WL .
PHYSICAL REVIEW LETTERS, 1985, 54 (20) :2246-2249
[5]   DELAYED IONIZATION OF C60 AND C70 [J].
CAMPBELL, EEB ;
ULMER, G ;
HERTEL, IV .
PHYSICAL REVIEW LETTERS, 1991, 67 (15) :1986-1988
[6]   MULTIPHOTON IONIZATION OF C60 [J].
DING, D ;
COMPTON, RN ;
HAUFLER, RE ;
KLOTS, CE .
JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (11) :2500-2504
[7]   CW LASER IONIZATION OF C-60 AND C-70 [J].
DING, D ;
HUANG, J ;
COMPTON, RN ;
KLOTS, CE ;
HAUFLER, RE .
PHYSICAL REVIEW LETTERS, 1994, 73 (08) :1084-1087
[8]  
Ertl G., 1985, Low Energy Electrons and Surface Chemistry Weinheim, P77
[9]   ELECTRONIC AND VIBRATIONAL STRUCTURE OF TRANSITION-METAL TRIMERS - PHOTOELECTRON-SPECTRA OF NI-3(-), PD-3(-), AND PT-3(-) [J].
ERVIN, KM ;
HO, J ;
LINEBERGER, WC .
JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (08) :4514-4521
[10]   Laser-induced optical-emission studies of niobium clusters [J].
Frenzel, U ;
Kalmbach, U ;
Kreisle, D ;
Recknagel, E .
SURFACE REVIEW AND LETTERS, 1996, 3 (01) :505-507