A convenient route to synthesize the fully conjugated bimetallic complex (Bu4N)2{tto[Ni(dmit)2]} (tto = tetrathiooxalate, C2S42-, and dmit=1,3-dithiole-2-thione-4,5-dithiolate, C3S52-) and the crystal structure of a new crystal form

被引：20

作者：

Bai, JF

Zuo, JL ^{[1
]}

Shen, Z

You, XZ

Fun, HK

Chinnakali, K

机构：

[1] Nanjing Univ, Inst Coordinat Chem, Nanjing 210093, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[3] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, Penang 11800, Malaysia

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 06期

关键词：

D O I：

10.1021/ic9902875

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A convenient and effective route to synthesize the fully conjugated bimetallic complex (Bu4N)(2){tto[Ni(dmit)(2)]}, the starting material for conducting conjugated bimetallic complexes [C](x){tto[Ni(dmit)(2)]}, has been developed. This new method is the direct conversion (Bu4N)(2)[Ni(dmit)(2)] into (Bu4N)(2){tto[Ni(dmit)(2)]} by dithionites. For the first time, the conversion of dmit(2-) into tto(2-) was realized. Also, the structure of a new crystal form of this complex was reported.

引用

页码：1322 / +

页数：4

共 25 条

[1] HIGHLY CONDUCTING CHARGE-TRANSFER COMPOUNDS OF TETRATHIAFULVALENE AND TRANSITION-METAL DMIT COMPLEXES [J].