Efficient catalysis of ammonia borane dehydrogenation

被引：551

作者：

Denney, Melanie C. ^{[1
]}

Pons, Vincent ^{[1
]}

Hebden, Travis J. ^{[1
]}

Heinekey, D. Michael ^{[1
]}

Goldberg, Karen I. ^{[1
]}

机构：

[1] Univ Washington, Dept Chem, Seattle, WA 98195 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 37期

关键词：

D O I：

10.1021/ja062419g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of an iridium pincer complex, dehydrogenation of ammonia borane (H3NBH3) occurs rapidly at room temperature in tetrahydrofuran to generate 1.0 equivalent of H2 and [NH2BH2]5. A metal borohydride complex has been isolated as a dormant form of the catalyst which can be reactivated by reaction with H2. Copyright © 2006 American Chemical Society.

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页码：12048 / 12049

页数：2

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