(1SR,2RS,5RS,6SR,8RS)-7,7-dimethyl- tricyclo[6.2.1.01,6]undecane-2,5,6-triol:: a supramolecular framework built from O-H ••• O hydrogen bonds

被引:1
作者
Mondal, S
Mukherjee, M [1 ]
Roy, A
Mukherjee, D
Helliwell, M
机构
[1] Indian Assoc Cultivat Sci, Dept Solid State Phys, Kolkata 700032, W Bengal, India
[2] Indian Assoc Cultivat Sci, Dept Organ Chem, Kolkata 700032, W Bengal, India
[3] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2002年 / 58卷
关键词
D O I
10.1107/S0108270102010843
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the title compound, C13H22O3, the asymmetric unit has two independent molecules linked by a strong O-H...O hydrogen bond. The cyclohexane ring is trans fused to the cyclopentane ring bridged through an ethyl moiety. The hydroxyl groups act as donors as well as acceptors, resulting in an extensive two-dimensional hydrogen-bonded network in the (011) plane. Intermolecular O-H...O bonds between centrosymmetrically related molecules form a four-membered supramolecular assembly, leading to infinite chains parallel to the [01 (1) over bar] direction, crosslinked in the [100] direction.
引用
收藏
页码:o474 / o476
页数:3
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