An MHD-based treatment of electrolysis in magnetic fields generated inside a solenoid

被引:15
作者
Fahidy, TZ [1 ]
机构
[1] Univ Waterloo, Dept Chem Engn, Waterloo, ON N2L 3G1, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
magnetoelectrolysis; magnetohydrodynamics; mass transport; solenoid; vorticity;
D O I
10.1023/A:1016584914107
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 [应用化学];
摘要
The effect of magnetic field superposition on electrolysis carried out in magnetic fields generated inside a solenoid is analysed using the theory of magnetohydrodynamics. It is shown that induced field inhomogeneity is responsible for the creation of local vortex motion which enhances ionic mass transport rates. A detailed vorticity analysis of two laboratory-scale, and a pilot plant-scale experimental magnetoelectrolytic cell serves for illustration.
引用
收藏
页码:551 / 559
页数:9
相关论文
共 33 条
[1]
[Anonymous], 1930, INTRO THEORY FOURIER
[2]
ELSASSER WM, 1957, MAGNETOHYDRODYNAMICS, P16
[3]
[4]
Fahidy TZ, 1999, MOD ASPECT ELECTROC, P333
[5]
WAVE PHENOMENA IN MAGNETOELECTROLYTIC SYSTEMS [J].
FAHIDY, TZ .
ELECTROCHIMICA ACTA, 1976, 21 (01) :21-24
[6]
HYDRODYNAMIC MODELS IN MAGNETOELECTROLYSIS [J].
FAHIDY, TZ .
ELECTROCHIMICA ACTA, 1973, 18 (08) :607-614
[8]
FAHIDY TZ, 2000, 4 INT PAMIR C MAGN D, V1, P351
[9]
GU ZH, 1988, INT J ENG FLUID MECH, V1, P1
[10]
Haase R., 1969, Thermodynamics of Irreversible Processes