Search for new modulations in the BiFeO3 structure:: SR diffraction and Mossbauer studies

被引:84
作者
Palewicz, A.
Szumiata, T.
Przenioslo, R.
Sosnowska, I.
Margiolaki, I.
机构
[1] Univ Warsaw, Inst Expt Phys, PL-00681 Warsaw, Poland
[2] Tech Univ Radom, Dept Phys, PL-26600 Radom, Poland
[3] European Synchrotron Radiat Facil, F-38043 Grenoble, France
关键词
multiferroics; SR diffraction; Mossbauer spectroscopy;
D O I
10.1016/j.ssc.2006.08.046
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
High resolution synchrotron radiation (SR) diffraction does not show any sign of charge ordering nor any crystal symmetry breaking in BiFeO3 at temperatures from 5 K up to 1000 K. The temperature dependence of the BiFeO3 lattice parameters shows a local minimum of the rhombohedral angle alpha(rh) around T-N suggesting a strong spin-lattice coupling. Mossbauer spectroscopy studies support the magnetic modulation of the hyperfine fields observed by NMR which are related to the modulated Fe3+ magnetic moments ordering observed by neutron diffraction. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:359 / 363
页数:5
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