Nanoscale battery materials based on the self-assembly of block copolymers

被引:14
作者
Bullock, SE
Kofinas, P [1 ]
机构
[1] Univ Maryland, Dept Chem Engn, College Pk, MD 20742 USA
[2] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA
关键词
impedance spectroscopy; microphase; polyelectrolyte;
D O I
10.1016/j.jpowsour.2003.12.045
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An ionically conducting block copolymer was used as a template for the synthesis and confinement of lithium manganese oxide nanoparticles. The block copolymer functions as a polyelectrolyte and as a composite anode in a lithium battery system. Impedance spectroscopy and galvanostatic testing, X-ray diffraction and transmission electron microscopy were used to characterize the anode and polyelectrolyte. Galvanostatic testing indicates 300 or more cycles were possible without appreciable capacity fade. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:256 / 260
页数:5
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