Recognition and sensing of fluoride anion

被引:637
作者
Cametti, Massimo [1 ,2 ]
Rissanen, Kari [2 ]
机构
[1] Univ Roma La Sapienza, I-00185 Rome, Italy
[2] Univ Jyvaskyla, Dept Chem, Nanosci Ctr, FIN-40351 Jyvaskyla, Finland
基金
芬兰科学院;
关键词
BOND-DISSOCIATION ENERGIES; CHARGE NEUTRAL THIOUREA; PUSH-PULL CHROMOPHORES; BIDENTATE LEWIS-ACID; DOT-CENTER-DOT; AQUEOUS-SOLUTION; SELECTIVE RECOGNITION; COORDINATION CHEMISTRY; BINDING PROPERTIES; CRYSTAL-STRUCTURE;
D O I
10.1039/b902069a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Fluoride anion recognition is attracting a mounting interest in the scientific community due to its duplicitous nature. It is a useful chemical for many industrial applications, and it has been used in human diet, but, recently it has been accused for several human pathologies. Here we describe the ample panorama of different approaches the chemists world-wide have employed to face the challenge of fluoride binding, and we outline some of the research which in our view can contribute to the development of this field, especially when fluoride binding has to be achieved in highly competitive protic solvents and water.
引用
收藏
页码:2809 / 2829
页数:21
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