Densities and viscosities for mixtures of pentyl acetate and hexyl acetate with normal alkanols at 298.15 K

被引:18
作者
ElBanna, MM
机构
[1] Department of Chemistry, Faculty of Education, Alexandria University, El-Shatby
关键词
D O I
10.1021/je960193z
中图分类号
O414.1 [热力学];
学科分类号
摘要
Densities and viscosities of the binary systems of pentyl and hexyl acetates with n-alkanols (ethanol, 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, 1-heptanol, and 1-octanol) have been measured at 298.15 K and atmospheric pressure, over the whole composition range. The excess volumes and change in viscosity have been obtained from the density and dynamic viscosity results. For all systems, the excess volumes are positive as the length of the hydrocarbon chain of the alkanol increases. The results of the viscosity-composition are discussed in the light of various viscosity equations suggested by Tamara and Kurata, Hind et al., McAllister, and Heric and Brewer.
引用
收藏
页码:31 / 34
页数:4
相关论文
共 17 条
[1]   EXCESS MOLAR VOLUMES AND VISCOSITIES FOR 1-PROPANOL AND 2-PROPANOL + METHYLACETATE SYSTEMS AT 298.15-K [J].
ACEVEDO, IL ;
POSTIGO, MA ;
KATZ, M .
PHYSICS AND CHEMISTRY OF LIQUIDS, 1990, 21 (02) :87-95
[2]   DENSITIES, VISCOSITIES, AND REFRACTIVE-INDEXES OF BIS(2-METHOXYETHYL) ETHER PLUS CYCLOHEXANE OR PLUS 1,2,3,4-TETRAHYDRONAPHTHALENE AND OF 2-ETHOXYETHANOL PLUS PROPAN-1-OL, PLUS PROPAN-2-OL, OR PLUS BUTAN-1-OL [J].
AMINABHAVI, TM ;
GOPALAKRISHNA, B .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1995, 40 (02) :462-467
[3]   DENSITY AND VISCOSITY OF OCTYL, DECYL, AND DODECYL SODIUM SULFATES IN ETHANOL [J].
ELBANNA, MM ;
RAMADAN, MS .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1995, 40 (02) :367-370
[4]  
Glasstone S., 1941, THEORY RATE PROCESSE
[5]   VISCOSITY OF SOME BINARY LIQUID NONELECTROLYTE MIXTURES [J].
HERIC, EL ;
BREWER, JG .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1967, 12 (04) :574-&
[6]   STRUCTURE AND VISCOSITY OF LIQUIDS - CAMPHOR+PYRENE MIXTURES [J].
HIND, RK ;
MCLAUGHLIN, E ;
UBBELOHIDE, AR .
TRANSACTIONS OF THE FARADAY SOCIETY, 1960, 56 (03) :328-330
[7]   SOLUBILITY OF THIOUREA IN C1 TO C6 1-ALCOHOLS [J].
KIM, KJ ;
LEE, CH ;
RYU, SK .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1994, 39 (02) :228-230
[8]  
MANICK JA, 1968, ALCOHOLS THEIR CHEM, pCH3
[9]   THE VISCOSITY OF LIQUID MIXTURES [J].
MCALLISTER, RA .
AICHE JOURNAL, 1960, 6 (03) :427-431
[10]   EXCESS MOLAR VOLUMES OF BINARY-MIXTURES OF ETHYL-ACETATE AND PROPYL ACETATE WITH NORMAL ALKANOLS [J].
ORTEGA, J ;
PENA, JA ;
PAZANDRADE, MI .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1986, 39 (10) :1685-1690