Fabrication and characterization of thin film electrolytes deposited by RF magnetron sputtering for low temperature solid oxide fuel cells

被引：55

作者：

Yoo, Yeong ^{[1
]}

机构：

[1] Natl Res Council Canada, ICPET, Ottawa, ON K1A 0R6, Canada

来源：

JOURNAL OF POWER SOURCES | 2006年 / 160卷 / 01期

关键词：

RF magnetron sputtering; thin film electrolyte; bilayered; low temperature solid oxide fuel cell;

D O I：

10.1016/j.jpowsour.2005.12.050

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Thin film solid electrolytes of La0.9Sr0.1Ga0.8Mg0.2O3-delta (LSGM), Sm0.2Ce0.8O1.9 (SDC), and Sc0.11Zr0.89O2-delta (ScSZ) were deposited by RF magnetron sputtering onto single crystal sapphire substrates as well as onto porous NiO-SDC anodes at deposition temperatures of RT <= T <= 500 degrees C. The electrical conductivities, phase analyses as deposited and after annealing and microstructures of the deposited thin film electrolytes were examined. In addition, the electrochemical performance of single cells composed of Sm0.5Sr0.5O3-delta (SSC)+SDC//SDC/ScSZ//NiO+SDC was demonstrated. Impervious and highly dense bilayer thin films of SDC and ScSZ have been successfully prepared on porous NiO-SDC anodes. Maximum power densities of 360 and 240 MW cm(-2) from single cells of Sm0.5Sr0.5O3-delta (SSC)+SDC//SDC/ScSZ//NiO+SDC were obtained at 600 and 550 degrees C, respectively, under humid 20% H-2 in Ar (3% H2O) and air. RF magnetron sputtering can be applied for depositing high performance thin film electrolytes in low temperature SOFCs. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：202 / 206

页数：5

共 14 条

[1] PORE NARROWING AND FORMATION OF ULTRATHIN YTTRIA-STABILIZED ZIRCONIA LAYERS IN CERAMIC MEMBRANES BY CHEMICAL-VAPOR-DEPOSITION ELECTROCHEMICAL VAPOR-DEPOSITION [J].

CAO, GZ ;

BRINKMAN, HW ;

MEIJERINK, J ;

DEVRIES, KJ ;

BURGGRAAF, AJ .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1993, 76 (09) :2201-2208

[2]

CASSIDY M, 1996, P 2 EUR SOL OX FUEL, P667

[3] SYNTHESIS AND CHARACTERIZATION OF YSZ THIN-FILM ELECTROLYTES [J].

CHEN, CC ;

NASRALLAH, MM ;

ANDERSON, HU .

SOLID STATE IONICS, 1994, 70 (pt 1) :101-108

[4] Metal-organic vapor deposition of YSZ electrolyte layers for solid oxide fuel cell applications [J].

Chour, KW ;

Chen, J ;

Xu, R .

THIN SOLID FILMS, 1997, 304 (1-2) :106-112

[5] Ceria-based solid electrolytes - Review [J].

Inaba, H ;

Tagawa, H .

SOLID STATE IONICS, 1996, 83 (1-2) :1-16

[6] ELECTRODE PERFORMANCE OF A THIN-FILM YSZ CELL SET ON A POROUS CERAMIC SUBSTRATE BY RF SPUTTERING TECHNIQUE [J].

NAKAGAWA, N ;

YOSHIOKA, H ;

KURODA, C ;

ISHIDA, M .

SOLID STATE IONICS, 1989, 35 (3-4) :249-255

[7] Solid oxide fuel cells with electrolytes prepared via spray pyrolysis [J].

Perednis, D ;

Gauckler, LJ .

SOLID STATE IONICS, 2004, 166 (3-4) :229-239

[8] The effect of deposition parameters on the properties of yttria-stabilized zirconia thin films [J].

Ruddell, DE ;

Stoner, BR ;

Thompson, JY .

THIN SOLID FILMS, 2003, 445 (01) :14-19

[9] Effect of CeO2 interlayer on ZrO2 electrolyte/La(Sr)CoO3 cathode for low-temperature SOFCs [J].

Shiono, M ;

Kobayashi, K ;

Nguyen, TL ;

Hosoda, K ;

Kato, T ;

Ota, K ;

Dokiya, M .

SOLID STATE IONICS, 2004, 170 (1-2) :1-7

[10] Electrode supported solid oxide fuel cells: Electrolyte films prepared by DC magnetron sputtering [J].

Srivastava, PK ;

Quach, T ;

Duan, YY ;

Donelson, R ;

Jiang, SP ;

Ciacchi, FT ;

Badwal, SPS .

SOLID STATE IONICS, 1997, 99 (3-4) :311-319

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