Preparation and structure of a macrocyclic thiocyanatotetraamine zinc(II) complex

被引：15

作者：

Choi, KY ^{[1
]}

Suh, IH ^{[1
]}

机构：

[1] CHUNGNAM NATL UNIV,DEPT PHYS,TAEJON 305764,SOUTH KOREA

来源：

POLYHEDRON | 1997年 / 16卷 / 14期

关键词：

macrocyclic thiocyanatotetraamine zinc(II) complex;

D O I：

10.1016/S0277-5387(96)00578-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [Zn(L-1)(NCS)][NCS] (1) (L-1 = 3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,0(1.18) 0(7.12)]docosane) has been prepared from the reaction of [Zn(L-1)(H2O)(2)][Cl](2) with sodium thiocyanate. The new complex has been characterized by spectroscopic and X-ray crystallographic methods. The crystal structure of 1 has revealed a five-coordinate, square-pyramidal geometry with an axial thiocyanate. (C) 1997 Elsevier Science Ltd.

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页码：2393 / 2396

页数：4

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