Preparation and structure of a macrocyclic thiocyanatotetraamine zinc(II) complex

被引:15
作者
Choi, KY [1 ]
Suh, IH [1 ]
机构
[1] CHUNGNAM NATL UNIV,DEPT PHYS,TAEJON 305764,SOUTH KOREA
关键词
macrocyclic thiocyanatotetraamine zinc(II) complex;
D O I
10.1016/S0277-5387(96)00578-5
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The complex [Zn(L-1)(NCS)][NCS] (1) (L-1 = 3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,0(1.18) 0(7.12)]docosane) has been prepared from the reaction of [Zn(L-1)(H2O)(2)][Cl](2) with sodium thiocyanate. The new complex has been characterized by spectroscopic and X-ray crystallographic methods. The crystal structure of 1 has revealed a five-coordinate, square-pyramidal geometry with an axial thiocyanate. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:2393 / 2396
页数:4
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