The study of hydrogen bonding and miscibility in poly (vinylpyridines) with phenolic resin

被引：92

作者：

Kuo, SW ^{[1
]}

Lin, CL ^{[1
]}

Chang, FC ^{[1
]}

机构：

[1] Natl Chiao Tung Univ, Inst Appl Chem, Hsinchu 30050, Taiwan

来源：

POLYMER | 2002年 / 43卷 / 14期

关键词：

hydrogen bonding; steric hindrances; effect polymer blend;

D O I：

10.1016/S0032-3861(02)00214-8

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The hydrogen bonding and miscibility behaviors of poly(2-vinylpyridine) (P2VP) or poly(4-vinylpyridine) (P4VP) with phenolic resin were investigated by differential scanning calorimetry and Fourier transform infrared spectroscopy (FTIR). These blends have a single glass transition over the entire composition range indicating that these blends are able to form a miscible phase due to the formation of intermolecular hydrogen bonding between hydroxyl of phenolic and pyridine ring of poly (vinylpyridines). Furthermore, FTIR studies on the hydrogen-bonding interaction between the hydroxyl group of phenolic and pyridine ring of poly (vinylpyridines) at various compositions and temperatures indicate that the greater inter-association for P4VP than P2VP due to the steric hindrance effect on specific interaction between these two polymers. Finally, inter-association equilibrium constants of phenolic/P2VP and phenolic/P4VP blends were determined by model compounds. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：3943 / 3949

页数：7

共 29 条

[1] MISCIBILITY AND SPECIFIC INTERACTIONS IN BLENDS OF POLY(HYDROXY METHACRYLATES) WITH POLY(VINYLPYRIDINES) [J].

CESTEROS, LC ;

MEAURIO, E ;

KATIME, I .

MACROMOLECULES, 1993, 26 (09) :2323-2330

[2]

COGGESTHALL ND, 1951, J AM CHEM SOC, V71, P5414

[3]

Coleman M. M., 1991, SPECIFIC INTERACTION

[4]

Coleman MM, 1999, MACROMOL CHEM PHYSIC, V200, P1167, DOI 10.1002/(SICI)1521-3935(19990501)200:5<1167::AID-MACP1167>3.0.CO

[5]

2-0

[6] HYDROGEN-BONDED POLYMER BLENDS [J].

COLEMAN, MM ;

PAINTER, PC .

PROGRESS IN POLYMER SCIENCE, 1995, 20 (01) :1-59

[7] Functional group accessibility in hydrogen bonded polymer blends [J].

Coleman, MM ;

Pehlert, GJ ;

Painter, PC .

MACROMOLECULES, 1996, 29 (21) :6820-6831

[8] Blends of polycaprolactone with polyvinylalcohol:: a DSC, optical microscopy and solid state NMR study [J].

De Kesel, C ;

Lefèvre, C ;

Nagy, JB ;

David, C .

POLYMER, 1999, 40 (08) :1969-1978

[9]

DEILARDUYA AM, 1995, MACROMOLECULES, V28, P3707

[10] FTIR and FT-Raman studies of partially miscible poly(methyl methacrylate)/poly(4-vinylphenol) blends in solid states [J].

Dong, J ;

Ozaki, Y .

MACROMOLECULES, 1997, 30 (02) :286-292

← 1 2 3 →