Gas-phase pyrolysis of 1-(2-azidophenyl)imidazole

被引：18

作者：

Blake, AJ

Clark, BAJ

McNab, H

Sommerville, CC

机构：

[1] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

[2] KODAK EUROPEAN RES & DEV,HARROW HA1 4TY,MIDDX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1997年 / 11期

关键词：

D O I：

10.1039/a700457e

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Flash vacuum pyrolysis (FVP) of the azide 4 leads to imidazo[1,2-a]benzimidazole 8 exclusively, via highly regioselective insertion of the triplet nitrene intermediate 5 into the 2-CH bond of the imidazole ring. The X-ray crystal structure and NMR spectroscopic properties of 8 are discussed in detail.

引用

页码：1605 / 1608

页数：4

共 13 条

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