Effective alkene epoxidation with dilute hydrogen peroxide on amorphous silica-supported titanium catalysts

被引：77

作者：

Capel-Sanchez, MC

Campos-martin, JM

Fierro, JLG

de Frutos, MP

Polo, AP

机构：

[1] CSIC, Inst Catalisis & Petroleoquim, E-28049 Madrid, Spain

[2] Ctr Invest & Desarrollo REPSOL YPF, Madrid 28045, Spain

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 10期

关键词：

D O I：

10.1039/b000929f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of amorphous silica-supported titanium catalysts in which the titanium ions display a chemical environment similar to that of Ti-substituted zeolites, afforded excellent activity in the epoxidation of terminal linear and bulky alkenes with dilute solutions of hydrogen peroxide.

引用

收藏

页码：855 / 856

页数：2

相关论文

共 12 条

[1] Spectroscopic characterization of silicalite-1 and titanium silicalite-1 [J].

Astorino, E ;

Peri, JB ;

Willey, RJ ;

Busca, G .

JOURNAL OF CATALYSIS, 1995, 157 (02) :482-500

[2] X-RAY PHOTOELECTRON-SPECTROSCOPY OF TI-BETA ZEOLITE [J].

BLASCO, T ;

CAMBLOR, MA ;

FIERRO, JLG ;

PEREZPARIENTE, J .

MICROPOROUS MATERIALS, 1994, 3 (03) :259-263

[3]

CAMPOSMARTIN JM, 1999, Patent No. 48884

[4] SYNTHESIS OF PROPYLENE-OXIDE FROM PROPYLENE AND HYDROGEN-PEROXIDE CATALYZED BY TITANIUM SILICALITE [J].

CLERICI, MG ;

BELLUSSI, G ;

ROMANO, U .

JOURNAL OF CATALYSIS, 1991, 129 (01) :159-167

[5]

FRIALE JM, 1995, J CHEM SOC CHEM COMM, P539

[6] DRS UV-VIS AND EPR SPECTROSCOPY OF HYDROPEROXO AND SUPEROXO COMPLEXES IN TITANIUM SILICALITE [J].

GEOBALDO, F ;

BORDIGA, S ;

ZECCHINA, A ;

GIAMELLO, E ;

LEOFANTI, G ;

PETRINI, G .

CATALYSIS LETTERS, 1992, 16 (1-2) :109-115

[7] NEW TIF4/SIO2 CATALYSTS FOR LIQUID-PHASE EPOXIDATIONS WITH AQUEOUS H2O2 [J].

JORDA, E ;

TUEL, A ;

TEISSIER, R ;

KERVENNAL, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (17) :1775-1776

[8]

Reddy JS, 1997, CHEM INDUST, V69, P405

[9]

SAXTON PJ, 1997, Patent No. 5621122

[10]

TAMURA M, 1996, Patent No. 0734764