Far-infrared electron-paramagnetic-resonance spectrometer utilizing a quasioptical reflection bridge

被引:52
作者
Earle, KA [1 ]
Tipikin, DS [1 ]
Freed, JH [1 ]
机构
[1] RUSSIAN ACAD SCI,INST CHEM PHYS,MOSCOW V334,RUSSIA
关键词
D O I
10.1063/1.1147205
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
We describe a far-infrared electron-paramagnetic-resonance (EPR) spectrometer for broadband (100-300 GHz) use. The spectrometer is operated in the reflection mode and uses broadband quasioptical methods to separate the transmitted from the reflected radiation. We describe and illustrate its operation at 170 GHz (1.8 mm) and compare its performance to that of our transmission mode spectrometer operating at 250 GHz. We also discuss the advantages of the reflection bridge for performing EPR experiments over a broad range of frequencies, and we consider methods of improving the performance of the bridge. This includes a novel design for variable coupling of the reflection-mode Fabry-Perot resonator. (C) 1996 American Institute of Physics.
引用
收藏
页码:2502 / 2513
页数:12
相关论文
共 34 条
  • [1] ALLGEIER J, 1990, MODERN PULSED CONTIN, pCH6
  • [2] [Anonymous], MILLIMETER WAVE OPTI
  • [3] Barnes J., UNPUB
  • [4] EPR SPECTROSCOPY AT VERY HIGH-FIELD
    BARRA, AL
    BRUNEL, LC
    ROBERT, JB
    [J]. CHEMICAL PHYSICS LETTERS, 1990, 165 (01) : 107 - 109
  • [6] THE OPTICAL-CONSTANTS OF SOME COMMON LOW-LOSS POLYMERS BETWEEN 4 AND 40 CM-1
    BIRCH, JR
    DROMEY, JD
    LESURF, J
    [J]. INFRARED PHYSICS, 1981, 21 (04): : 225 - 228
  • [7] QUASI-OPTICAL MIRRORS MADE BY A CONVENTIONAL MILLING MACHINE
    BOUCHER, D
    BURIE, J
    BOCQUET, R
    CHEN, WD
    [J]. INTERNATIONAL JOURNAL OF INFRARED AND MILLIMETER WAVES, 1992, 13 (09): : 1395 - 1402
  • [8] FULL DETERMINATION OF THE ROTATIONAL DIFFUSION TENSOR BY ELECTRON-PARAMAGNETIC RESONANCE AT 250 GHZ
    BUDIL, DE
    EARLE, KA
    FREED, JH
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (07) : 1294 - 1303
  • [9] FREE-STANDING FINE-WIRE GRIDS - THEIR MANUFACTURE, PERFORMANCE, AND USE AT MILLIMETER AND SUBMILLIMETER WAVELENGTHS
    COSTLEY, AE
    HURSEY, KH
    NEILL, GF
    WARD, JM
    [J]. JOURNAL OF THE OPTICAL SOCIETY OF AMERICA, 1977, 67 (07) : 979 - 981
  • [10] Doane J. L., 1985, MILLIMETER COMPONENT, P123